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DYNAMERS: dynamic polymers as self
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Importing self-repair or self-healing features into inert materials is of great relevance to material scientists, since it is expected to eliminate the necessity of replenishing a damaged material. Be it material chemistry or more specifically polymer chemistry, such materials have attracted the imagination of both material scientists and chemists. A stroll down the memory lane 70 years back, this might have sounded utopian. However with the current progress in supramolecular chemistry and the emergence of dynamic covalent and non-covalent chemistries, novel perspectives have been opened up to materials science towards the development of dynamic materials (DYNAMATS) and in particular dynamic polymers (DYNAMERS), with the ability to produce such species by custom made designs. Chemistry took giant strides to gain control over the structure and features of materials and, besides basic progress, to apply it for tailor-making matter for applications in our daily life. In that applied perspective, materials science plays a paramount role in shaping our present and in contributing to a sustainable future. The goal is to develop materials, which would be dynamic enough to carry out certain functions as effectively as in biological systems with, however, the freedom to recruit the powers of chemistry on a wider scale, without the limitation imposed by life. Material scientists and in particular polymer chemists may build on chemistry, physics and biology for bridging the gap to develop dynamic materials presenting a wide range of novel functionalities and to convert dreams into reality. In this current review we will focus on developments in the area of dynamic polymers, as a class of dynamic materials presenting self-healing features and, more generally, the ability to undergo adaptation under the effect of physical and/or chemical agents, and thus function as adaptive polymers or ADAPTAMERS.
中文翻译：
将自我修复或自我修复的特征导入惰性材料中对材料科学家来说意义重大，因为这有望消除补充损坏材料的必要性。无论是材料化学还是更具体的高分子化学，此类材料都吸引了材料科学家和化学家的想象。沿着70年前的记忆小道漫步，这听起来像是乌托邦式的。但是，随着超分子化学的最新进展以及动态共价和非共价化学的出现，材料科学对动态材料（DYNAMATS）尤其是动态聚合物（DYNAMERS）的开发有了新的视角，并具有通过定制设计生产此类物种。化学在控制材料的结构和特征方面取得了长足的进步，除基本进展外，还将其应用于量身定制的物质中，以应用于我们的日常生活中。从这种应用的角度来看，材料科学在塑造我们的现在并为可持续发展的未来做出贡献方面发挥着至关重要的作用。目的是开发材料，这种材料具有足够的动态性，可以像生物系统一样有效地执行某些功能，但是可以自由地在更广泛的范围内招募化学力量，而不受生命的限制。材料科学家，特别是高分子化学家可以在化学，物理和生物学的基础上建立桥梁，以开发具有广泛新颖功能的动态材料，并将梦想转化为现实。适配器。 |
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